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I wouldn't try it, since it would probably result in a relatively thick baby powder barrier. I would actually suggest using pure baby powder applied with a dry cottonball, so the barrier is thinner and thus more slippery. But to answer your question, yes, and vodka would probably work a bit better ...

Hello,
It is very hard for me to find rubbing alcohol in my country and I was wondering if it is possible to replace it with vodka?
Vodka + baby powder?